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Deoxygenation of solvents and aq. solutions   Message List  
Reply | Forward Message #90 of 188 |
Dear all:

I may need to deoxygenate solvents and some aqueous solutions to determine
the conten o fhydroperoxides in my samples by purging with nitrogen.
I have read that 30 min is suitable for volumes of 50-100 mL of some
solvents. However, there are many factors affecting the removal of oxygen,
and both the conssumption of nitrogen and the loss of solvents may be
significant.
Therefore, I am interestined in finding if there is any kinetic study
concerning deoxygenation of different systems or alternatively if there any
easy and cheap method to control the amount of residual oxygen that is left.

Thanks in advance,

Juan

Juan José Rodríguez Herrera
Dpto. Química y Tecnología de Productos Pesqueros
(Dpt. of Chemistry and Technology of Fish Products)
Instituto de Investigaciones Marinas
(Institute of Marine Research)
Consejo Superior de Investigaciones Científicas (C.S.I.C)
36208 VIGO
ESPAÑA (SPAIN)





Tue Sep 24, 2002 1:37 pm

juan@...
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Message #90 of 188 |
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Dear all: I may need to deoxygenate solvents and some aqueous solutions to determine the conten o fhydroperoxides in my samples by purging with nitrogen. I...
Juan José Rodrí...
member; u=12...
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Sep 24, 2002
3:12 pm

I would suggest that you use vaccum de-air and break with nitrogen at least three time before bubbling with nitrgoen. Also, if you may be better off to remove ...
Linsen Liu
member; u=77...
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Sep 25, 2002
8:30 am

Several device may be found to deoxygenate solvents. The best for HPLC is to use an on line vacuum instrument able to manage 4 lines of solvents. With the help...
Claude Leray
member; u=75...
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Sep 27, 2002
8:39 am
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